I don't think so, it looks like that might have to be done entirely via the programming API, and you need an application registered to do so (or the access token of another application) because it only works on one application: http://developers.facebook.com/docs/test_users/
You can definitely create a user and then turn him into a test account manually, I've created many test accounts that way. You have to visit a special URL that turns the account into a test account (can't remember it offhand, and I'm not going to post it anyway since if anyone clicks on it then clicks "accept" without looking, it nukes their regular account).
Test accounts can't interact with real Facebook users, but they can be used to log in to sites.