I realize MBAs have a bad rap (disclaimer, I'm getting my MBA), but I think they can bring a lot of variety to the start-up scene. The MBA class is chock full of students from almost every industry who know very well the problems these respective industries face. Furthermore MBAs approach problems through different lenses that may be more sensitive to firm strategy, finance, operations, accounting, etc. These approaches may uncover new insights into the business or market.
@Dwollb I'm also getting my MBA, and agree with you. There is a propensity for MBAs to get a bad rap in this community. I came into my program (Kellogg) with a tech background, and I know it has radically changed how I approach problem solving and other tasks.