Failures are just a property of distributed systems, some fail in ways that are better for you, some fail in ways that are worse, but sooner or later they all fail. It's a tradeoff which one you choose.
MongoDB was tested in a replicated setup, PG not, that's a pretty fundamental difference. Loosing acked writes in a master-slave replication with failover would be expected with a sufficiently large replication lag even for PG.
MongoDB is about the last database I'd pick for any given scenario, but I acknowledge that there are people that have a usecase where it might be a good fit because the tradeoffs work out for them.
Failover is documented to not work very well in MongoDB (data loss): http://aphyr.com/posts/284-call-me-maybe-mongodb
On the postgres side RepMgr makes dealing with replication quite easy: https://github.com/2ndQuadrant/repmgr
See also this recent thread on the PostgreSQL mailing list: http://postgresql.nabble.com/Fully-automatic-streaming-repli...