I will certainly take a look at Qt, and other alternatives, but isn't Visual Studio the ultimate tool of all tools? I'd rather start with it from the start, since I'm already familiar with most of the programming paradigms and stuff that isnt tied to language itself, so it's just a matter of learning cpp + IDE, and I figured out I can easily enough start out with VS? Maybe it will have a bit slower learning curve than if i start with Qt, but at the end it will pay off.
Well, in all the C++ universe Visual Studio is a nice tool, but no one will hire anyone for knowing how to use it. It's the libraries and programming language skills that matter.
Qt is like VCL and it can be used within VS or without it. The Microsoft equivalent to VCL is MFC, but I don't think that's a very current skill to have. It's also the opposite of RAD, having to write lots of boilerplate to get something on the screen. I mean that's why MS invented .NET, MFC was unproductive.