Personally, i find the python documentation a little overwhelming, while i found PHP's much clearer and more straightforward, despite learning PHP first. Much easier to figure out something quickly. Its hard to pin down but if i had to i'd say it can be too verbose, there can be too much on a page, and too little white-space. I'd also like to see it more example driven.

Having said this i rarely if ever hear any criticism of the python docs from others.

E: sorry, why was stating my opinion, when sought, deserving of downvoting? If you disagree then say so-- i even stated i thought my opinion was a minority one!