It's the opposite; I prefer DuckDB and generally work with DuckDB's friendly SQL interface. SQL is declarative and is (for me) more intuitive than method-chaining -- especially for complex analytic operations that happen in one go.
(software people might beg to differ about the intuitive bit because they are more used to an imperative style, and to my surprise, even the best software engineers struggle with SQL because it requires one to think in set and relation operations rather than function calls, which many software folks are not used to)
I actually don't use the Polars dataframe APIs much except for some operations which are easier to do in dataframe form, like applying a Python function as UDF, or transposing (not pivoting) a dataframe.
Also Polars is good for materializing the query into a dataframe rapidly, which can then be passed into methods/functions. It's also a lot easier to unit test dataframes than SQL tables. There's a lot more tooling for that.