Seems like an obvious selection bias, IMO - much like chess or RTSs or first person shooters. The kind of geeky person who plays Magic and has the brains to do very well even against fellow geeks - is it such a surprise that a good fraction of them might do well when they turn their efforts to poker or finance?
He's referring to how the most popular Bitcoin exchange site, mtgox.com was formerly a trading site for Magic The Gathering cards, "Magic The Gathering Online eXchange"
This site was hacked a few days ago causing much chaos in the Bitcoin community.