One reason for providing this is so that you can have an alias like
alias mv '\mv -=myfavoritearg '
No; quoting any part of the command name prevents alias expansion. Eg 'mv', "mv", 'm'v, m\v, etc all work.
I've always used /bin/mv or /bin/ls to get just the command, but your method is shorter. (although I can't help but think of windows paths)