It's one of the most influential papers in epistemology. The paper gave rise to the notion of the "Gettier problem" for the otherwise appealing view that knowledge is justified true belief. A great deal of epistemology since can be understood as trying to figure out what to add to the "justified true belief" theory to get around Gettier-style objections.
Also interesting, it seems to have been basically the only thing he published, and he published it mainly because he had to publish something.
http://www-bcf.usc.edu/~kleinsch/Gettier.pdf