I don't think anyone has. When it's that dark you get a free light show courtesy of your eyes. It was quite disconcerting the first time it happened to me.
Stars put out quite a bit of light in remote areas, cloud cover may block ~75% of this, but it's still far from 'pitch black'. One of the stranger things about caving is it just keeps getting darker as you go deeper.
PS: As a kid I used to spend a lot of time walking around in starlight. I only ever really used a flashlight inside. I moved much closer to a city and light pollution is terrible to the point where there is little need to turn lights on in my apartment unless I want to read something.
Regardless, I don't think many city dwellers have ever experienced pitch black.