There is a substantial difference between these two links. One takes you to a location, the other one starts a process which ends with an action.
As a user you are not going to be clicking the “New” button everyday. Maybe once a month, maybe once a year. So you are likely not going to remember where it is from the last time you clicked it. If you don’t find it when you need it, you will get frustrated. It needs a lot of visual weight relative to the other links in this nav section. Giving the same weight as a button is a reasonable decision.
As a user you are not going to be clicking the “New” button everyday. Maybe once a month, maybe once a year. So you are likely not going to remember where it is from the last time you clicked it. If you don’t find it when you need it, you will get frustrated. It needs a lot of visual weight relative to the other links in this nav section. Giving the same weight as a button is a reasonable decision.